Chemicals used in hydraulic fracturing

i Mar 24th No Comments by

In 2011 the US House of Representatives Committee on Energy and Commerce asked 14 leading oil and gas service companies to disclose the types and volumes of the hydraulic fracturing products they used in their fracking fluids between 2005 and 2009.

The resulting report can be accessed here.

The relevant extract from the Executive Summary reads [emphasis added]:

“Between 2005 and 2009, the 14 oil and gas service companies used more than 2,500 hydraulic fracturing products containing 750 chemicals and other components. Overall, these companies used 780 million gallons of hydraulic fracturing products – not including water added at the well site – between 2005 and 2009.

Some of the components used in the hydraulic fracturing products were common and generally harmless, such as salt and citric acid [though do you want these added to your groundwater?]. Some were unexpected, such as instant coffee and walnut hulls. And some were extremely toxic, such as benzene and lead.

The most widely used chemical in hydraulic fracturing during this time period, as measured by the number of compounds containing the chemical, was methanol. Methanol, which was used in 342 hydraulic fracturing products, is a hazardous air pollutant and is on the candidate list for potential regulation under the Safe Drinking Water Act.

“Between 2005 and 2009, the oil and gas service companies used hydraulic fracturing products containing 29 chemicals that are (1) known or possible human carcinogens, (2) regulated under the Safe Drinking Water Act for their risks to human health, or (3) listed as hazardous air pollutants under the Clean Air Act. These 29 chemicals were components of more than 650 different products used in hydraulic fracturing.

“The BTEX compounds – benzene, toluene, xylene, and ethylbenzene – appeared in 60 of the hydraulic fracturing products used between 2005 and 2009. Each BTEX compound is a regulated contaminant under the Safe Drinking Water Act and a hazardous air pollutant under the Clean Air Act. Benzene also is a known human carcinogen. The hydraulic fracturing companies injected 11.4 million gallons of products containing at least one BTEX chemical over the five year period.

“In many instances, the oil and gas service companies were unable to provide the Committee with a complete chemical makeup of the hydraulic fracturing fluids they used. Between 2005 and 2009, the companies used 94 million gallons of 279 products that contained at least one chemical or component that the manufacturers deemed proprietary or a trade secret. Committee staff requested that these companies disclose this proprietary information. Although some companies did provide information about these proprietary fluids, in most cases the companies stated that they did not have access to proprietary information about products they purchased “off the shelf” from chemical suppliers. In these cases, the companies are injecting fluids containing chemicals that they themselves cannot identify. “